comparative
English adjectives of three or more syllables, like "difficult," form their comparative with "more" rather than an -er ending, so "more difficult" is the correct, natural-sounding form, while adding -er directly to a long word produces something no native speaker would actually say.
"Difficulter" simply isn't a word English speakers use — the language reserves -er endings mainly for short, one- or two-syllable adjectives — and "most difficult" is the superlative form, used for comparing three or more things rather than just two.
The rough rule of thumb — short adjectives take -er, long ones take "more" — has exceptions and gray areas around two-syllable words, which is why comparatives remain one of the trickier corners of English grammar for learners to master.
comparative
Some comparatives are irregular. What's the comparative of 'good'? 'This one is ___ than that.'Quration — Quration English